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Different manufacturers make different variations of bullet-resistant glass, but it is basically made by layering a polycarbonate material between pieces of ordinary glass in a process called lamination. This process creates a glass-like material that is thicker than normal glass. Polycarbonate is a tough transparent plastic -- often known by the brand name Lexan, Tuffak or Cyrolon. Bullet-resistant glass is between 7 millimeters and 75 millimeters in thickness. A bullet fired at a sheet of bullet-resistant glass will pierce the outside layer of the glass, but the layered polycarbonate-glass material is able to absorb the bullet's energy and stop it before it exits the final layer.
The ability of bullet-resistant glass to stop a bullet is determined by the thickness of the glass. A rifle bullet will collide with the glass with a lot more force than a bullet from a handgun, so a thicker piece of bullet-resistant glass would be needed to stop a rifle bullet as opposed to a handgun bullet.
There is also one-way bullet-resistant glass available, which has one side able to stop bullets, while the other side allows bullets to pass through it unaffected. This gives a person being shot at the ability to shoot back. This type of bullet-resistant glass is made by laminating a brittle sheet of material with a flexible material.
Imagine a car equipped with this one-way bullet-resistant glass. If a person outside the car shoots a bullet into the window, the bullet would strike the brittle side first. This brittle material would shatter around the point of impact and absorb some of the energy over a large area. The flexible material then absorbs the remaining energy of the bullet, stopping the bullet. A bullet fired from inside the same car would easily pass through the glass because the bullet's force is concentrated on a small area, which causes the material to flex. This causes the brittle material to break outwards, allowing the bullet to pierce the flexible material and strike its target.