The force of air pressure depends on two things:
Most of the time we don't notice air pressure because there is air all around us. All things being equal, air particles will disperse evenly in an area so that there is equal air density at every point. Without any other forces at work, this translates to the same air pressure at all points. We aren't pushed around by this pressure because the forces on all sides of us balance one another out. For example, 14.7 psi is certainly enough to knock over a chair, or crush it from the top, but because the air applies roughly the same pressure from the right, left, top, bottom and all other angles, every force on the chair is balanced by an equal force going in the opposite direction. The chair doesn't feel substantially greater pressure from any particular angle.
So, with no other forces at work, everything would be completely balanced in a mass of air, with equal pressure from all sides. But on Earth, there are other forces to consider, chiefly gravity. While air particles are extremely small, they do have mass, and so they are pulled toward the Earth. At any particular level of the Earth's atmosphere, this pull is very slight -- the air particles seem to move in straight lines, without noticeably falling toward the ground. So, pressure is fairly balanced on the small scale. Overall, however, gravity pulls particles down, which causes a gradual increase in pressure as you move toward the earth's surface.
In the next section, we'll explore how this works.
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